Exposure to sunlight causes the body to make vitamin D (which isn't really a vitamin, but more of a hormone). This is great news for vegans, since dietary vitamin D can be tricky to obtain except via supplementation (though omnivores are equally deficient in vitamin D in higher latitudes).
So we need to revel within the Goldilocks Zone of sun exposure. Sunscreen manufacturing is a billion dollar industry. It's up to you what kind you choose. Chemical sunblocks have not been adequately tested for safety in my opinion, so given the alternatives, I'll choose a titanium dioxide variety that creates a physical barrier. Confused about types of sunscreen? There are many articles like this one from the Wall Street Journal that explain the basic options.
Which sunscreens are vegan? Here is PETA's list, some more popular options rounded up at One Green Planet, and this list from The Vegan Woman that covers the US, Europe, and Australia. I'm not uber-brand-loyal, I just look for a "vegan" or "cruelty-free" label. I've liked Green Screen Organic and right now I've got a tube of this California Baby sunscreen in the car with a very mild lemongrass scent (they also make a fragrance-free super-sensitive variety).
Timing outdoor activities on normal days to coincide with non-peak exposure is also a helpful strategy. Try aiming for before 10am and after 4pm, depending on the time of year. Also, wearing light-colored light-weight long sleeves or pants may be an option depending on your climate and comfort.
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